In the present work, powder diffraction patterns from cellulose Iα, Iβ, II, III I, and III II were calculated based on the published atomic coordinates and unit cell dimensions contained in modified “crystal information files” (.cif) that are supplied in the Supplementary Information. In part, this desirable connection is thwarted by the use of different conventions for description of the unit cells of the crystal structures. However, the connection is seldom made between those efforts and the crystal structures of cellulose that have been proposed with synchrotron X-radiation and neutron diffraction over the past decade or so. The (1-10) and (110) peaks of cellulose IB remained near the Segal amorphous location of cellulose II for blends of control and mercerized cotton fibers.Cellulose samples are routinely analyzed by X-ray diffraction to determine their crystal type (polymorph) and crystallinity. Despite this underestimation, the relatively good agreement of the Segal method with the simulation for mercerized cotton was attributed to the incomplete conversion to cellulose II. For cellulose II, the effect of peak overlap was smaller however the lower reflection of the amorphous cellulose scattering in its Segal amorphous location resulted in smaller Segal amorphous fractions. Although the amorphous fraction was set in the simulation, the peak overlap induced by the increase of FWHM further enhanced the Segal amorphous intensity of cellulose IB. The higher Segal amorphous fraction for control cotton was attributed to the peak overlap. Their Segal amorphous fractions were 15% and 31%, respectively. The diffraction patterns of control and mercerized cottons, respectively, were simulated with perfect crystals of cellulose IB (1.54' FWHM) and cellulose II (2.30o FWHM) as well as 10% and 35% amorphous celluloses. To address the dependency of Segal amorphous intensity on crystal size, cellulose polymorph, and the degree of polymorphic conversion, we simulated the diffraction patterns of cotton celluloses (IB and II) and compared the simulated amorphous fractions with the Segal values. Technical Abstract: The Segal method estimates the amorphous fraction of cellulose IB materials simply based on intensity at 18o 20 in an X-ray diffraction pattern and was extended to cellulose II using 16o 2O intensity. These results are expected to be informative in obtaining unbiased CI values of cellulose materials after physicochemical or biological treatments. The simulation of the X-ray diffraction patterns of control and mercerized cotton celluloses suggested some aspects that should be considered in measuring or interpreting the Segal CI values: (a) a pressed powder type of sample was recommended by comparison with a nonwoven fabric type, because the preferred orientation suppressed the (012) and (102) peaks of cellulose I' located near the Segal amorphous location (b) the Segal method may not be appropriate for partially mercerized samples, because the (1-10) and (110) peaks of cellulose I' remained near the Segal amorphous location of cellulose II (c) the Segal CI depended on FWHM (i.e., crystal size) and cellulose polymorph and (d) the Segal method underestimated the amorphous fraction for cellulose II, because its Segal amorphous location failed to measure the major intensity of amorphous cellulose. Interpretive Summary: Due to its simplicity, the Segal crystallinity index (CI) has been used widely to measure the relative crystalline (or amorphous) fraction in cellulose I' and II materials, but its accuracy is controversial. Segal crystallinity index revisited by the simulation of x-ray diffraction patterns of cotton cellulose IB and cellulose II. Citation: Nam, S., French, A.D., Condon, B.D., Concha, M.C.
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At night the infected roam the streets freely searching for prey, presenting opportunities for you to explore areas of the city inaccessible by day. Society exists in the relative safety of sunlight, while the infected hide in the shadows of buildings. THE INFECTION HAS EVOLVED The infection has evolved and become more sensitive to UV light. This is a violent, primal & unforgiving world - and so are its inhabitants. Civilization is gone but the relics are still there. A MODERN DARK AGE In a desperate city, where resources and power are scarce, unstable, and trust in ruling bodies is all but eroded humankind has reverted to a dark age. EXCEPTIONAL AGILITY AND BRUTAL COMBAT On your journey from humble beginnings to a person of great power, you have unprecedented freedom of movement across the city, seamlessly integrated with brutal first person combat. Host your own games or join other players' and see how their choices have played out differently to your own. Play the entire campaign in up to four-player co-op. The effect of the choices you make will have a huge impact on entire regions of the city, uncovering new land masses and areas to explore. YOUR CHOICES, YOUR WORLD You must make tough decisions and hard sacrifices as you decide the fate of a society on the brink of collapse. With your unique abilities you have the power to be an agent of change within this decaying metropolis. Your exceptional agility and brutal combat skills make you a powerful ally and a valuable commodity in this dangerous world. You are Aiden Caldwell, an infected survivor. At night the infected roam free, evacuating their dark hideouts to prey on the living. During the day, bandits, factions and starving survivors roam the streets scavenging for scraps - or someone to take them from, by violence if necessary. The last great human settlement exists within an unforgiving, infected world, plunged into a modern dark age. During the day, bandits, factions and starving survivors roam the streets scavenging for THE FATE OF THE CITY IS IN YOUR HANDS It's been 15 years since humanity lost to the virus. Summary: THE FATE OF THE CITY IS IN YOUR HANDS It's been 15 years since humanity lost to the virus. Looking around, Matthew saw that there was. Snip scapes finely into softened butter, and spread on baguettes to make a less pungent version of garlic bread.Īs with many culinary delicacies, the season for scapes is short and sweet. The concept of Farm-Scape was coined in 2012, when Matthew, our Proprietor, was living in the desert southwest. Replace basil leaves with chopped scapes in our seasonal pesto recipe Or enjoy them like we cook them in the restaurant by dipping scapes into a tempura batter, deep-frying, and serving with a sweet chilli sauce. We offer on farm pickup every Friday, but our newsletter also offers a look into the rhythms of. With a fresh, garlic taste they are perfect for summer salads and for cooking. The idea of the game is to restore the area into a dream village via decorations. Celebrate seasonality, by learning what is available each week. Garlic Scapes are the flower of the garlic plant. Players will join Mary in her efforts to turn an abandoned farm into a rustic paradise. Stir-fry a bunch of scapes, and serve them with a garlicky aioli dipping sauce. Free-to-play specialist Playrix has soft-launched a new farming-based match-three puzzler known as Farmscapes. Lightly fry the chopped scape stalks, then scatter them into salads or stir through pasta dishes So if you grow your own garlic at home, you can trim the scapes away, knowing that you are both maximising your garlic bulb's potential, whilst harvesting a gourmet delicacy for the next meal. These tender green stalks are both edible and delicious, rather like tender, young asparagus with a delicious hint of garlic flavour. Youll love this special blend of match 3, hidden object, and simulation Breathe new life into your Farmscapes, complete with clucking chickens, mooing cows and buzzing beehives. Left to their own devices, garlic scapes would ultimately produce tiny bulbs of their own, or 'bulbils' but because these divert food and energy away from the star attraction, here at The Isle of Wight Garlic Farm we prefer to snip the scapes off, enabling the garlic bulbs to increase in size - sometimes allowing them to grow another 50%! Happily though, the scapes don't go to waste. Earn money by selling fresh veggies, juicy fruits, eggs, flowers and honey to the townspeople, and spend your cash to restore the land to its former glory. You may not take images or content from this site without written permission.Before hardneck garlic bulbs (such as Elephant Garlic, Caulk Wight, Lubasha Wight and Kingsland Wight) fully mature and are ready to be harvested, they throw out long, curly scapes, which hold the flower head of the plant. We have partnered with Proven Winners & Walters Gardens to bring you these incredible Perennial Garden Recipes - complete with plant lists, quantities. We design, install and maintain lush, sustainable gardens that combine food crops with native, low-water landscaping ideal for California’s summer-dry climate. Help Joe restore his ranch Breathe in new life into a formerly prosperous farm in Farmscapes, a fun Match 3 game Earn money by selling fresh veggies, juicy. © Golden Earthworm Organic Farm, LLC 2002-2023. Our Long Island based CSA / Farm Share Program serves members with neighborhood delivery of our organic food in the following communities in Nassau & Suffolk County: Massapequa, Massapequa Park, Levittown, Bethpage, Plainview, Rockville Centre, Seaford, Valley Stream, Wantagh, Cold Spring Harbor, Glen Head, Glen Cove, Great Neck, Huntington, Port Jefferson, Port Washington, Ridge, Saint James, Setauket, Northport, Smithtown, Stony Brook, Hicksville, Holbrook, Medford, Syosset, Williston Park, Jamesport, Riverhead, Mattituck, Cutchogue, Greenport, Westhampton, Westhampton Beach, Moriches, East Quogue, Quogue and Southampton, Floral Park, Little Neck. Find out why more Long Islanders trust us to feed their families.īecause of our PASSION FOR ORGANICS, our FAIR PRICES and our ORGANIC FARMING EXPERIENCE.Ĭelebrating 29 years of Certified Organic Farming on the North Fork of Long Island! Mario Kart 8 Deluxe Booster Course Pass Regular Price: 24. You may have to select a menu option or click a button. If you do not have a Nintendo Switch Online + Expansion Pack membership, learn how to sign up. Follow the instructions for disabling the ad blocker on the site you’re viewing.You may have more than one ad-blocker installed. You’ll usually find this icon in the upper right-hand corner of your screen. Click the icon of the ad-blocker extension installed on your browser. When it turns gray, click the refresh icon that has appeared next to it or click the button below to continue.Click on the large blue power icon at the top.Click the UBlock Origin icon in the browser extension area in the upper right-hand corner.It will turn gray and the text above will go from “ON” to “ OFF”. Click on the “ Ad-Blocking” button at the bottom.Click the Ghostery icon in the browser extension area in the upper right-hand corner.Switch off the toggle to turn it from “ Enabled on this site” to “ Disabled on this site”.Click the AdBlocker Ultimate icon in the browser extension area in the upper right-hand corner. Mario Kart 8 Deluxe is an upgraded version of the Nintendo Switch, released worldwide in April 2017.“ Block ads on – This website” switch off the toggle to turn it from blue to gray.Click the AdBlock Plus icon in the browser extension area in the upper right-hand corner.Refresh the page or click the button below to continue.Under “ Pause on this site” click “ Always”.Click the AdBlock icon in the browser extension area in the upper right-hand corner.In other gaming news, 343 Industries has fixed Halo Infinite‘s Battle Pass progression issue.Īdblock Adblock Plus Adblocker Ultimate Ghostery uBlock Origin Others While it is usually $100 USD, the game can now be purchased at a 40% discount at $60 USD. Perhaps the game that has received the biggest discount of all includes Mario Kart Live: Home Circuit, a game that essentially turns the home into a real-life Mario Kart course. Many titles for Nintendo are also on sale including Breath of the Wild, New Super Mario Bros U Deluxe, Splatoon 2, SuperMario Maker 2 and Paper Mario: The Origami King. The two add-ons normally cost $68 USD, but with the Black Friday bundle, it is now included in the Switch console price of $300 USD. It is important to note that this is only applicable for the regular Switch and not the OLED edition, which costs $50 USD more than the original. Download Torrent ID 010075100E8EC000 (Chinese) Base (Dumped) XCI 6.88 GB 1Fichier OLD Update Update 2.2.1 NSP 1.87GB 1Fichier Update 2.2.0 NSP 2.62GB 1Fichier Update 2.1.0 NSP 1.19GB 1Fichier DLC Booster Course Pass NSP 118KB 1Fichier Update 2.0.0 NSP 630.5MB 1Fichier Update 1.7. Packaged with the purchase of the Nintendo Switch, fans will receive a digital copy of the popular Mario Kart 8 Deluxe as well as three months of Nintendo Switch Online. This year, the Black Friday bundles see Nintendo offer a nearly identical one to last year’s. Quotations are used to search for an exact phrase. This search string will return any results with Recruitment Manager and any results with Recruitment Consultant. So the search becomes: Recruitment AND (Manager OR Consultant). In Boolean search, it is similar in that, the section inside the brackets always takes priority over the other elements.įor example when you enter Recruitment AND Manager OR Consultant, are you asking the search to prioritise Recruitment AND Manager or Manager OR Consultant? By using brackets, you can easily explain to the search engine how you want the search string to be read. The important rule being that the calculation inside the brackets always comes first. Brackets ()īrackets are used in a very similar way to the rules of the BODMAS acronym that you might still remember from your high school maths lesson. You can also use the minus symbol followed by your unwanted term (without leaving a space between both). NOTĪs you can probably estimate, the NOT operator is used to exclude specific requirements. So a search for Recruitment OR Manager will return any results containing Recruitment and any results containing Manager. It can be useful when different words to say the same thing, for example, Recruitment AND (Manager OR Consultant OR Agent OR Advisor) 3. With the OR operator, you are requesting the search you want to see multiple entries in the results, and used to expand your Boolean search results. By inputting a search for Recruitment AND Manager, you are requesting results with both Recruitment and Manager in it. The AND operator is generally used to narrow your search results. The AND operator is used when you want to include two (or multiple) criteria in your Boolean search. So what are they? The 6 Basic Boolean Search Operators For Recruiters 1. Below is a real life example of a search string constructed to search for a Senior Financial Analyst:Īnaly* NEAR Financ* AND (Retail* OR e-commerce OR ecommerce) AND budget* AND Plan* AND forecast* AND risk* AND Excel AND (PowerPoint OR “Power Point” OR Tableau OR SAP) AND (Access OR SQL OR “BO” OR “Business Objects”)Īlthough this looks complicated, by breaking it down into its individual operators, it only utilises the 6 basic operators in a Boolean search. Once you have exhausted your standard CV and profile searches, conducting more specific Boolean searches can be a dynamic alternative that may unearth hidden talent that isn’t easily accessible through common search function.īoolean literate recruiters can perform incredibly complicated search strings to meet your every job requirement. Using Boole’s laws, recruiters can refine their search results in a number of ways which can be particularly effective for finding a range of active and passive candidates for your open vacancies. What Is Boolean Search In Recruitment?īoolean search in recruitment is the act of leveraging large databases, such as your recruitment CRM, LinkedIn, Indeed, or for Google to perform specific searches in order to find relevant candidates quickly. That is why Google paid its own special tribute in 2015 to mark Boole’s 200th birthday, demonstrating how his laws work:īut before losing yourself in the never ending animation, let’s explain what Boolean search is in recruitment and how it is used effectively. It is an astonishing thought but, without his laws, Google would never have existed in the way we know it today. The laws of Boolean search were invented by English Mathematician George Boole in The Mathematical Analysis of Logic (1847) and have become a fundamental building block for all digital devices. In fact, as a recruiter, it is probably something you use everyday without even realising it. And for a web designer, you can use (web OR designer OR developer OR UI OR UX) AND (HTML OR CSS OR JavaScript OR jQuery OR Bootstrap) AND (Photoshop OR Illustrator OR Sketch OR Figma OR Adobe XD) AND (portfolio OR samples OR examples OR links).Boolean search in recruitment is not a modern concept. When searching for a cybersecurity specialist, you can use (cybersecurity OR security OR cyber OR infosec) AND (analyst OR engineer OR consultant OR specialist OR manager) AND (CISSP OR CISM OR CEH OR OSCP OR SANS) AND (firewall OR network OR malware OR encryption OR penetration testing). For a data analyst, you can use (data OR analyst OR scientist OR engineer) AND (SQL OR Python OR R OR SAS OR SPSS) AND (Excel OR Tableau OR Power BI OR Qlik) AND (statistics OR analytics OR machine learning OR data mining). For instance, when looking for a software engineer, you can use (software OR developer OR engineer OR programmer) AND (Java OR Python OR C# OR Ruby) AND (SQL OR MongoDB OR MySQL OR Oracle) AND (HTML OR CSS OR JavaScript OR React OR Angular). When recruiting for different roles and industries, you can use various combinations of keywords and operators to create Boolean search strings. (17) Business & Finance (17) Slang, Chat & Pop culture (8) Sort results: alphabetical | rank ?The bar is a metric unit of pressure, but not part of the International System of Units (SI) it is defined as exactly equal to 100,000 Pa (100 kPa). madera craigslist What does BAR stand for? Your abbreviation search returned 69 meanings Link/Page Citation Information Technology (6) Military & Government (16) Science & Medicine (13) Organizations, Schools, etc. And lest you think this place is too dapper to play ball, note that its namesake, Cubs hall-of-famer Mordecai Brown, was a particularly badass three-fingered pitcher. Does a Barback Have to Be 21? The illuminated back bar is armed with flat screens for game day, hidden slyly behind sliding gold circular screens designed to look like a baseball hurtling toward home. If you wanted to get a sense of what it’s like working in a bar or club before seeking a barback position, you could start as a busser, server, or host in any establishment that serves food as well as alcohol. Hiring bars may look for experience in foodservice, especially previous positions in bars or clubs. The File Explorer icon is a yellow folder that, when opened, will let you browse through the content of your computer. 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So, 9 bars of pressure means that the machine is creating 9 times the atmospheric pressure at sea level. One bar is equal to the atmospheric pressure at sea level, which is about 14.7 psi or pounds per square inch. The term “bar” is a unit of measure just like “mph” or “kilograms.” It’s a way of quantifying pressure.By the barometric formula, 1 bar is roughly the. A pressure of 1 bar is slightly less than the current average atmospheric pressure on Earth at sea level (approximately 1.013 bar). What bar The bar is a metric unit of pressure, but not part of the International System of Units (SI) it is defined as exactly equal to 100,000 Pa (100 kPa). Battery What happens if my battery isn't working? Please email us your order number and photos of the Defect/Damage for review by our quality assurance department. I received a Defective/Damaged item, what do I do? USPS What is Always Timeless's return policy?Īt this time Timeless does not offer returns or exchanges. What shipping carrier does Always Timeless use? Does Always Timeless offer expedited shipping?Īt this time we do not offer expedited shipping at this time. What does Timeless charge for shipping?Īt this time our shipping rates are based on weight. Orders from Always Timeless take 5-8 days to process. Shipping & Returns How long will my order take? Do you have an event calendar?Ĭheck out our Events page for more info and be sure to sign up for our Newsletter to hear the latest from Always Timeless. Please reference individual code fine print for more info. Please email us at with your question and be sure to include your order number! What are your coupon code policies?Ĭodes can not be combined or applied to previous purchases. You will find our products are never affected by the passage of time or change in trends… we are always Timeless.General I have a question about my order. Our patient-first mentality is reflected in our philanthropy and local outreach events, having made community education and charitable fundraising a cornerstone of our philosophy. Order Noir Skywalker OG Timeless Carts Online This is the reason that you will “Taste the Terps” while enjoying your Timeless Vape experience. We believe in putting our patients first, with our Timeless Vapes never containing solvents or fillers and only using all- natural Terpenes to enhance our product. The Timeless proprietary blend features a solvent-free THC distillate, crafted for a consistent, high-quality product with extraordinary flavor profiles. Our medical-grade materials and cutting-edge hardware and technology crafted in the USA provide unrivaled quality and performance. Noir Skywalker OG Timeless Carts for Sale Online We took special consideration to keep both you and your Timeless Vape clean with the Timeless Flip Case, fashioned specifically for discretion while medicating. Buy Noir Skywalker OG Timeless Carts OnlineĮach aspect of the Timeless Vape experience has been crafted with discretion and quality in mind. Our passion has always been research and development, constantly striving to create the highest quality and most innovative products available. Timeless Vapes was founded in 2013 with the vision of giving patients an efficient and subtle way to medicate. The resulting Skywalker Kush inherited an incredibly high THC concentration and distinctly sour hashish aroma that consumers covet.Īt Timeless Vapes, our mission is to provide the cleanest and most effective cannabis medicine while striving to set the standard of excellence in an ever-growing industry. The team dusted a female Skywalker OG, which is itself OG Kush crossed with Skywalker, with pollen from OG Kush, which boasts Chemdawg and Lemon Thai in its lineage. Skywalker Kush is the creation of the breeders at Reserva Privada, and was first grown in Southern California. Time to complete this macro photography course:Įvery student is different but in general we think the whole course will take around 13 hours 35 minutes to complete including: You'll also learn how to work safely at night and how to set up a mini macro studio on a table for still life studies also how to gain a white background for objects to display on websites or for promotional photos. You will appreciate just how effective a reflector, a diffuser or fill-flash can be at changing the light how to use depth of field creatively and how to meter tricky low key and high key subjects. Amongst these are examples of patterns and designs. Images range from flowers, leaves, seeds, fruits and aquatic life to coins, glass, jewellery and food. using ambient light (and modifying light).The great thing about working at close range is that macro photography subjects are everywhere, you just have to develop a seeing eye for beauty, texture and design. Heather will share her secrets behind some of her memorable macro shots and offer tips and hints for shooting macro outdoors and inside. When you take macro photographs you'll often reveal unexpected shapes, colours or patterns and details you can't see with the naked eye. Macro photography is the art of producing photos of small objects (often every day items or insects) at a larger than life size. To learn that technique and watch a macro pro take pictures of jumping spiders, click here.Photographer Heather Angel teaches you the art of macro photography, from using your camera for macro photos to finding creative inspiration for the best close-up shots. To get truly sharp and crisp macro pictures you may need to use a technique called handheld stacking. The key here is to know when it’s going stay still when it’s still, grab that picture! Before you try to get a photograph spend time watching the movement of the spider and notice its actions. You will find them crawling out of small cracks and holes in wood and brick. Clearly this movement makes them very difficult to photograph. You see them when the day heats up and with the heat comes active movement. Jumping spiders for instance, will not be found on cold mornings. Spiders are very different to butterflies in terms of movement and activity. In particular, the famous jumping spiders! It takes patience, plenty of practice and an understanding of the species you want to photograph. Spiders are extremely difficult to photograph which is why it’s a must for any aspiring macro photographer, to get a picture. A bit like how you would move a magnifying glass.Īfter a few practice runs this effective technique will create stunning results. Then get them as close to your water droplet set up as possible without losing focusģ > Then move the background subject towards and away from the water droplets until it looks sharp within them. Doing this inside is a good idea to avoid unnecessary movement created by gusts of windĢ > Set up your camera and macro lens on a tripod. It takes a bit of practice and a lot of patience but here’s the technique:ġ > Put water droplets on something that will not move. The refraction of light in its simplest term is the bending of light as it passes from one transparent substance into another.īy placing an object or picture behind a water droplet, you will be able to capture that subject refracted in the water droplet. There’s a lot of room to be creative when it comes to photographing water droplets and, in this example, we will use them to refract light. Checkmating your opponent should be your top priority since this will ensure your victory. When a checkmate happens, the game ends immediately, and the player who delivered the checkmate wins. The basic start position in chess is like this: See the chess position below. A checkmate (also known as 'mate') occurs when a king is placed in check and has no legal moves to escape. You got 1 King, 1 Queen, 2 Rooks, 2 Bishops, 2 Knights and 8 Pawns on 64 squares. This documentation covers all related templates. When a king is attacked, it is called check. Half of the 64 squares are called light squares, while the others are known as dark squares. The default template for a standard chess board is. The chessboard is an 8x8 grid of alternating colored squares. These templates shows a chess diagram, a graphic representation of a position in a chess game, using standardised symbols resembling the pieces of the standard Staunton chess set. Marvel Comics from DC and issues 23 from Marvel as Marvel Comics vs. Each company would publish two issues of the miniseries, thus the title difference between issues 1 and 4 as DC vs. The series presented dream match-ups for fans like Hulk vs. The stakes couldn’t be higher as each reality fought for its survival. #pov #titans #dccomics #marvel #mcu #marvelcomics #marvelcinematicuniverse #dcuniverse #crossover #crossovertok #crossoverpov #marvelpov #mcupov #titanspov #dcpov #titanstok #marveltok #dctok #mcutok #titanstvshow #netflixtitans #blackwidow #gotg #guardiansofthegalaxy #natasharomanoff #gamora #richardgrayson #nightwing #jasontodd #redhood #batman #koryanders #koriandr #starfire #rachelroth #raven #friendstvshow #joeytribbiani #chandlerbing #monicageller #sleepclinic #foryoupage #fyppage #fypppageee #foryou #fypシ #fypp #fypage #foryourpage #forupage #forryouu #fyppageforyouġ09 Likes, TikTok video from Grayson's & Todd's bf "#pov #titans #dccomics #marvel #mcu #marvelcomics #marvelcinematicuniverse #dcuniverse #crossover #crossovertok #crossoverpov #marvelpov #mcupov #titanspov #dcpov #titanstok #marveltok #dctok #mcutok #titanstvshow #netflixtitans #blackwidow #gotg #guardiansofthegalaxy #natasharomanoff #gamora #richardgrayson #nightwing #jasontodd #redhood #batman #koryanders #koriandr #starfire #rachelroth #raven #friendstvshow #joeytribbiani #chandlerbing #monicageller #sleepclinic #foryoupage #fyppage #fypppageee #foryou #fypシ #fypp #fypage #foryourpage #forupage #forryouu #fyppageforyou". DC) is a comic book miniseries intercompany crossover published by DC Comics and Marvel Comics from April to May 1996. Marvel and DC treated 90s fans with a winner-take-all bout between the heroes of each universe. |
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